Hi,
The supply to the analogue section is generally the same voltage level as the main chips supply. (just cleaner hopefully)
If you want to measure voltages greater than this generally you use a resistive voltage divider into a rail-to-rail non-inverting op-amp connected to the ATD input.
The divider changes the 5V to 3 or so volts, then the buffer which is fed from the same analogue supply as the micros ADC section buffers it and provides a low source impedance to the ADC.
Hope that helps
Peg