Hello Dao,
There is a Kinetis Peripheral Module Quick Reference document (Also known as: KQRUG) http://cache.nxp.com/files/32bit/doc/quick_ref_guide/KQRUG.pdf which shows intialization code/snipped codes for different module on Kinetis K family MCU. There is a section for ENET module and shows a basic initialization code.
However, besides configuring ENET module you will need to create you own stack in order to communicate through ethernet interface. Ethernet specifies its own layer communication (OSI module) and every layer has its own header/information (You can check the answer from Mario Castañeda: https://community.nxp.com/thread/391187 ). So, you will need to create your own ethernet stack and that will imply a lot of effort. That is why all examples/documentation about sending data through ethernet uses either RTCS (MQX) or lwIP (also there is a FNET stack which in standalone version: FNET Embedded TCP/IP Stack).
In summary, I would strongly suggest to move to another solution (Kinetis SDK, MQX) which includes support for ethernet and other stacks such as FatFS, USB, etc.
I hope this can help you!
Regards,
Isaac