Hi,
Regarding the baudrate of usart, I suppose that you use traditional uart protocol, in other words, you connect TX, RX and GND between LPC55S16 USART and host USART, whether you can communicate between two USART reliably is only dependent on the the match degree of the driving clock of two USART modules, give an extreme example, if the two USART module(one is transmitter, another is receiver) use the same driving clock, in other words, the two USART module driving clock is 100% match, you can get very high baud rate.
Hope it can help you
BR
XiangJun Rong