Hello David,
Each pin can used not only one function.
For example the pin94(100-pin part) (PIO0_18)you mentioned, you can configure it as U0_RXD function,
also can used to CT32B0_MAT0, or gpio PIO0_18.

For some customer, they may be used this pin as CT32B0_MAT0 function, then they only can use the pin20 as U0_RXD. If there is only one U0_RXD, how does customer use UART0 if the only pin has been used.
Have a great day,
TIC
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