There is not current a "Wiring" framework for the Freedom yet, but I am working on it.
(Many do not realize it, but the Arduino API is actually the based on the Wiring Framework)
Extended Framework (API) \ Wiring
You will will now have an 800+ document, that at first will be, well some what overwhelming.
I suggest for now you learn how the use Processor Expert (aka PE), as you will first need to approach this at a high level.
Erich has some excellent tutorials for PE.
The KL25 is based on ARM M0+, which in turn is based on ArmV6, so you may wish to google these documents:
DDI0484B_cortex_m0p_r0p0_trm.pdf - Cortex-M0+ Technical Reference Manual
and
DDI0419C_arm_architecture_v6m_reference_manual.pdf - ARMv6-M Architecture Reference Manual
Freescale does not fully explain the architecture as it is based on these documents.
You also may wish to try out Keil uVision MDK which is free up to 32K. I prefer Codewarrior, but right now 10.3 is in beta has issues that are blocking me. MDK 100% supports the OpenSDA and the Freedom board.