Hello again @Pavankumar1 ,
The ADC by default has a variability of the values taken, in this case the gain error typically is -0.16 %FSV according to the table 76 in the datasheet. Also, the ADC has another variability because this range is near of 0 V, this variability is typically +-0.01%FSV as mentioned in the data sheet.
This happens because the response of the ADC ceases to be linear as it approaches one of the limits of its range, Also, around 0 V the noise affects more to the conversion.
Also, if you experience any issue, do not hesitate to let me know.
BR
Habib.