Hello @florian_arndt, here Jorge.
Here is an update from the internal team.
As it has indicated in the datasheet, the Tr and Tf value shall refer to Section 3.5.
According to Section 3.5 description shown below, the Tr and Tf depend on the load capacitance (CL) on the IO and its drive strength (output resistance).

According to the RC charge/discharge circuit and equation shown below, the rising and falling time between 20% and 80% OVDD is [Tr = Tf = 1.39RC], where R is the output resistance and C is the load capacitance (CL).
According to the Drive Strength setting and its corresponding output current table shown below, the minimum output resistance of the IO at Fast slew rate mode is around [(1.8V / 10.5mA + 3.3V / 20.6mA) / 2 = 165Ohms] and the maximum output resistance of the IO at Fast slew rate mode is around [(1.8V / 5.27mA + 3.3V / 10.3mA) / 2 = 330Ohms].


Suppose the load capacitance is 50pF, the minimum Tr and Tf would be [Tr = Tf = 1.39 x 165Ohms x 50pF = 11.5ns] and the maximum Tr and Tf would be [Tr = Tf = 1.39 x 330Ohms x 50pF = 23ns].
Best regards.