Hi,
I support iMX products, but have used the PF0100 in several designs, so although not an expert on its operation my understanding is as follows -
The default table shown above assumes SW3 to be in single phase mode, your hardware is configured for independent mode, for single phase SW3BFB should be left floating, your design has it connected to the SW3B output, so I'm assuming this is where the trouble lies.
All of this is from the PF0100 datasheet, rev 16, I would suggest you review this document again and make sure you understand all the set ups and settings.
Your design is configured as independent -

but the default register setting expects single phase -

If you wanted to test this, looking at your schematic snippet attached I think you can convert from independent to single phase by -
- Removing L6 (and most likely FB13, not sure if you have anything connected to the SW3B output)
- Shorting SW3BLX (one of the L6 pads) to the SW3AFB net
- Possibly you may need to remove C170, C171, C229 (requirement is to have SW3BFB open circuit, don't think the capacitors would be an issue, could try without removing first, if still an issue remove)
This should let you see 1.5V at SW3AB, with 2.5A capability.
To use your independent configured set up I believe you will have to reprogram one register value containing the SW3_CONFIG setting -

Can be found here -

Hope this helps.
Ross