i.MX6 supports MIPI, LVDS, Parallel(RGB) and HDMI interface for display.
If the NTSC encoder supports RGB as input interface, you can output RGB data from i.MX6 to NTSC encoder and then NTSC encoder can outputs analog signal as your requirement.
For software view, you need to care about the below
1. Make sure the output RGB data of i.MX6 is correct for the input of NTSC encoder.
2. Right settings for NTSC encoder configuration.