Hi @Nibesh,
The boot process is explained in the RM, Section 25.3.3 Boot sequence.
It takes 325us from the point VDD reaches 2.7 V to execution of the first instruction across the operating temperature range of the chip.

Then, it is given by the execution time of the custom SW that jumps to the application from the bootloader.
Program Section execution time (1KB flash) is time that the FTFC takes to program 1KB of flash, it has nothing to do with the boot process.
Regards,
Daniel