Hi @WUXIE,
You can have the pin configured as GPIO OUTPUT (muxed to the GPIO module), and trigger ADC conversions on that pin (always muxed, connected during the sampling).
But the pull device gets disabled when the pin is an OUTPUT.
RM, rev.14, Section 12.6.1 Pin control

What is the use case here?
Why do you need one pin to be internally pulled while the output push-pull driver is enabled, and use it as an digital input at the same time.
And on top of that, trigger ADC conversions on that pin?
Regards,
Daniel