Hello,
Is the micro-controller standalone enough for peripheral redundancy, i.e in case of any peripheral failure, like sci. Will the micro-controller switch to a new sci port?
No. This is the task for your SW. Micro will detect the failure.
Does the micro-controller ASIL-D compatible

Not sure what you mean by compatible. But it is supporting many tests in HW. I'd say it is ASIL-D ready.
If it is ASIL-D compatible, would it be achieved by the software of the micro-controller itself?
Combination of SW and HW. For example lock-step is HW feature.
Is it a ASIL-D device compliant and ASIL-D systematic compliant micro-controller?
Not sure what you mean here. But customers use this device in ASIL-D class applications. We provide the SW like SAF (safety applciation framework) to help customers achive ASIL-D.
More details and safety documents you will find here:
https://community.nxp.com/t5/SafeAssure-Community-Knowledge/REQUESTING-ACCESS-for-Safety-material-at...
Best regards,
Peter