Hi Edward,
thanks for your response.
Actually, I dont want to repurpose SS. I want to SPI with 3 lines, so I save 1 line.
So spec. says this is possible with CPHA = 1:

and that is what I want to do.
Now, if I understood your 2nd paragraph, your concern is regarding initial synchronization. Currently, I am testing this with 2 Hearst devel boards, so I can force SPI Slave to run first, then I turn on the SPI Master, therefore initial sync should not be a problem.
Nevertheless, SPI Slave is not receiving properly nor responding.
P.S. tL is minimum leading time, therefore can be greater, and that is the case in my start procedure; it is also not required in back-to-back.