Sorry, I cannot really help because I don't understand the problem.
I'm not sure what you did, somehow it sounds as if you would have changed the defines in the derivative header file.
As far as I know, those are there to be used, but out of the box, no one is using them. So writing wrong values into them wont help at all, it just make hard to track problems in the future.
There are really many ways to program the vectors. If this is about how to define the COP vector in addition to the reset vector, I would say, do it the same way for the cop as you did it for the reset vector. (maybe a VECTOR entry in the prm?), then add the same for the COP and all the other vectors you need (with an adapted vector number or vector address, of course).
Daniel