I need at least one extra pair in the CAT5 cable for power, and there are only 4 pairs available.
Hello Charlie,
You can use it with 2 pairs. You check the schematics in datasheet Fig 18 and the OM6293 evaluation board User Guide for the PCA9600 which can be helpful.
https://www.nxp.com/docs/en/data-sheet/PCA9600.pdf
https://www.nxp.com/docs/en/user-guide/UM10323.pdf
I hope this can be helpful. Please let me know if you have further questions.
Have a great day,
Paulina