Hi pingli,
First of all, sorry for delays but your questions have been initially posted into another community.
Your issue looks very much the same with this one: Something wrong happens when starting SIL or PIL simulation
As you can see for the your error message, your Operation System does not recognize the spaces in the path and it is splitting the "Program Files" into 2 separate paths that does not exist.
One simple thing to try would be to install the toolbox into C:\NXP\MBDToolbox folder.
If that error still persist then you might need to have a loop of the thread mention above and enable the 8dot3 option
Regarding the second question: are you looking for this one: S32K144 Evaluation Board|NXP
Hope this helps!
Daniel