After rebuilding index, highlighting function and pressing <F3> twice navigates to function definition. First press of <F3> only navigates to function prototype. I always used to navigate to function definition on first press of <F3>.
In my workspace I have Three projects. Two library projects and One application project.
I right-click on each project - Index - Rebuild
My indexer window is as follows:

On first press of <F3> I can navigate to function definition when function call and function definition reside in application.
But it takes two <F3> presses to navigate to function definition when function call is in application and function definition is in library.