Hi @limingzhou
All LPC55S3x security documents are posted on the device homepage
https://www.nxp.com/products/LPC553x#myDocument
Select "Secure" option, you will see the list

LPC55S36 has PSA level 3 certificate, see declaration here
https://products.psacertified.org/products/lpc55s36
Regarding to your Q2 of boot time, The LPC55S3x supports booting from internal flash, external flash, or ISP mode, depending on configuration. the boot time information is not documented in any existing files. So I suggest you creating a private ticket to request it. Please address your project information and why this information is necessary to you in your ticket. Our support team will get back to you for it.
Thanks,
Jun Zhang