Hi,
Regarding your question, as you have seen that the OPAMP output pin and DAC pins are shared with ADC analog channels, but both the OPAMP and DAC can be disabled, in the case, you can connect analog source to the ADC analog pins which are shared with OPAMP output pins or DAC output pins.
From the following screenshot I copied from LPC553XRM.PDF, for the LPC5536 with QFP100 package, there are total 23 single-ended analog channels, among of them there are 9 differential channels. Of course, because the DAC output pin is shared with ADC analog channel, if you use one DAC output, the ADC analog channels you can use becomes to 22.
Regarding the PWM, there are two eFlexPWM modules, one SCTimer module and 5 Ctimer modules, the two eFlexPWM can generate at least 2*8=16 PWM channels, the SCTimer can generate 10 PWM signals, so it is okay for the PWM.

Hope it can help you
BR
XiangJun Rong