Hi, Benton,
For 64 pin package chip of LPC550x family, there are 9 ADC channels, for the 48 pin package chip of LPC550x family, there are 7 ADC channels.
Regarding the two ADC analog channels pin which are multiplexed with SWD pins:
PIO0_12/ADC0_10/.../SWDIO, and PIO0_11/ADC0_9/..../SWCLK, when you design your development board, I suggest you use a jumper, in detail, you can connect the two pins to the SWD connector directly and connect the two pins to ADC analog signal via jumper. In development stage, you can open the jumper, download/debug without considering the two analog channels. After your project has finished, close the jumper while disconnect the SWD device. You can use a resistor to replace the jumper.
Hope it can help you
BR
XiangJun Rong