Hello Andree,
1. Yes, it can generate a 100 Hz signal . which freescale example do you mentioned ?
If you install KDS IDE, you can create one PE project ,then you can easily configure the PWM frequency to 100hz :

2. About your this question "acquire a sensor signal only when the previous signal is high", do you want
capture the high signal ? You can use the capture mode of Timer:

You can also use one GPIO input interrupt function. If i misunderstand your meaning , please tell me .
About the synchronize the TPM signal with the ADC , how about in the TPM interrupt start the ADC .
Hope it helps
Have a great day,
Alice
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