Hi @jh0
I hope you are doing well
Regarding your questions:
>>What pins are not in high impedance state after power up?
Please refer to the table Signal Multiplexing and Pin Assignments table of the DS , and check the Default column, there you can see specifically which pins are DISABLED at power up.
DISABLED indicates no function after reset, so that is High-Impedance.
>>In my case I am measuring 0-7V, so there is voltage divider, and measured value is OK. I don't have place on PCB for external clamp diodes. Current to DAC is limited (by divider) to 0.5 mA. I guess that this is safe without using external diodes.
It is hard to tell if your system will be immune to transient over voltages. The external clamp diodes are a good safety feature to have.
>>There are lot of pins with default ADC ALT state, and by note 'Since the ADC pins do not have diodes to VDD, external clamp diodes must be included to protect against transient over-voltages' it means that all this pins are not protected? Even not used for ADC?
The ADC pins ( and all I/O ) still have an clamping diode to VSS for ESD protection. As this note from the datasheet indicates: All I/O pins are internally clamped to VSS through a ESD protection diode.
>>ADC pins (default ALT) are in Hi-Z??
Pins that have the default ALT as ADC , are not in Hi-Z
>>What will be if 5V signal (limited to 1mA) is connected to micro pin (in default Hi-Z state) while VDD is 1.8V?
This will be out of the specification, When a pin is on a high impedance state , the voltage applied to the pin must not get above VDD+ .3.
>>What is situation with empty (not existing / connected) ALT. For example with selected not-existing ALT7 pin will be ih Hi-Z?
That alternative will disable the pin, so it will be in Hi-z.
If you have more questions, do not hesitate to let me know.
Diego