The K64 RTC is just a counter -- accuracy is entirely up to the crystal specs and as tuned with the onchip caps. I get about 1sec/day (11.6ppm). You can 'do better' compensating for TC, but 'only while the CPU is running' (say you wake up every hour and adjust the caps OR the 'compensation reg'). I don't use the compensation reg, mostly because I am extrapolating the prescaler counts to time 'tens of microseconds' at the lowest level, and that math requires 32768 counts per second.
My XTAL = Abracon ABS10-32.768KHZ-7-T +/-20ppm, another 0 to -20ppm 10C to 50C
I set the chip caps to 8 pf.