I've checked my MCF5329 Reference Manual. It uses 0xA0 as well. Those values correspond to setting the IEN and MSTA bits, and makes a lot more sense than the obviously wrong one in the MCF5485 manual. The latest manual is Revision 5.
The current "MCF5485RMAD.pdf (Reference Manual Errata) says of the Revision 5 manual "None to report". You've found one!
Searching on Freescale for 'I2CR = 0xA" gets 40 hits, as does searching for "I2CR = 0xA0". The Search can't be made specific enough to catch this difference.
Letting Acrobat search through my own copies shows the 5301x, 5373, 54455, 52223, 52211, 5282, 5275, 52235, 52277, 5213, 5208, 5235 and 5329 manuals are OK. The 5307, 5475 and 5485 ones are wrong. The 5307 one is ancient (stamped "Motorola") and is probably where the 547x manuals were copied from.
Tom